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Glossary of Terms

Anode a. The site in a corrosion cell where the consumption of metal occurs.
b. The positive current source introduced for a Cathodic protection system. May be galvanic or impressed current anode.
Carbonation The process where carbon dioxide (CO2) reacts with water in concrete pores to form carbonic acid, neutralizing the high alkaline concrete, possibly causing corrosion of reinforcement.
Cathodic Protection (CP) The process in which a metal structure is protected from corrosion using either galvanic (sacrificial) or impressed current anodes. Metal becomes Cathodic and is protected from corrosion.
Cathodic Prevention Name given to Cathodic Protection of a new (usually concrete) structure where the CP is installed at the time of construction. Less current is required to protect the structure in these systems, resulting in a more economical outcome than later installation of CP.
Chloride Corrosion Chloride is an aggressive ion that is responsible for initiating many corrosion problems, especially in concrete structures exposed to seawater or chloride rich environments.
Chloride Extraction The electrochemical process of removing Chloride ions from a concrete structure (similar arrangement to CP) in a corroding structure. Treatment commonly takes 4 to 8 weeks.
Concrete Mixture of cement (Portland cement), sand, aggregates and water resulting in a reaction of the water and the cement to form a hard binder.
Corrosion The process where a metal reverts back to its natural state by oxidation (rusting). Requires oxygen and water.
Electrochemical The process of using an electric current to move ions. Cathodic protection, realkalization, chloride extraction are all electrochemical processes.
Half cell Often a pure metal in a solution of fixed concentration, giving a reaction of a steady potential. Reference half cells are used to measure the “corrosion potential” of a metal or steel reinforcement in concrete.
Impressed Current
Cathodic Protection
A type of Cathodic Protection where a direct current power supply (transformer rectifier) provides power to an invert anode to pass current protecting a metal (making the metal Cathodic)
Ion An atom which has gained or lost electrons (eg Na+,Cl-,Fe2+)
Passivation Process by which a metal is protected from corrosion by a passive layer usually due to a highly alkaline environment. (eg reinforcing steel is passivated by the alkaline nature of concrete being pH ~12)
pH Measure of acidity and alkalinity (neutral 7, acid 0-7, alkaline 7-14)
Prestressing The process where a compressive stress is applied to concrete by the stressed (stretched) wires or bars of steel. (Prestressed or post-tensioned) Extreme care must be taken in the Cathodic protection of prestressed steel due to the possibility of causing hydrogen embrittlement in the steel, resulting in brittle failure of the prestressed reinforcement.
Reference electrode Another name for a half cell
Reinforced concrete Concrete containing reinforcing steel. Concrete is strong in compression but weak in tension. Reinforcement adds tensile strength to concrete.
Realkalization An electrochemical process (sometimes referred to as desalination) in which carbonated concrete is treated in a process similar to Cathodic protection, to restore the alkalinity and stop corrosion of the reinforcing steel. The process takes 3 to 7 days in most cases.
Rust Corrosion product of a metal as it corrodes

Sacrificial Cathodic
Protection

A type of Cathodic Protection where a more easily corroded metal (anode) is connected to the metal being protected. Common sacrificial anodes are zinc, aluminium or magnesium (or alloys of these metals) which sacrifice themselves to protect the metal (steel) being protected. The sacrificial anode is consumed and may need to be replaced in time.
Titanium anode Titanium is “activated” in a coating process resulting in an invert material ideal for long term use as an impressed current anode. Commonly used as anodes for the protection of reinforced concrete and steel structures in water or soil.

 

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